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Wash and dry hands. Use water to keep fire exposed containers cool. On standing, especially in the cold, may become cloudy, and on exposure to very low temperature ppt of trioxymethylene formed; in air it slowly oxidizes to formic acid /40% solution/. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Flammable/combustible material. P308+P313 IF exposed or concerned: Get medical advice/ attention. Remove contaminated clothes. Evacuate personnel to safe areas. Homes in which UFFI was installed many years ago are not likely to have high formaldehyde levels now. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). For personal protection see section 8. Metals such as platinum, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. Remove gas with fine water spray. Maintain open airway and assist ventilation if necessary. 1B (H314), Skin Sens. Formaldehyde may also be used under restriction in the EUas a preservative in cosmetics and nail hardening products. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. The main products are carbon monoxide and hydrogen. Water spray may be used to flush spills away from exposures and to dilute spills to nonflammable mixtures. A person conducting a business or undertaking (PCBU) must correctly labelhazardous chemicals used, handled or stored at the workplace, including containers and pipework. Gas. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Effects in women include menstrual disorders and secondary sterility. 1B (H350) Concentration: < 5% Component: Methanol CAS No: 67-56-1 EC No: 200-659-6 Index No: 603-001 -00-x Registration No: 01-2119433307 -44-xxxx Classification: Flam. Fire will produce irritating, corrosive and/or toxic gases. Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. Component: Formaldehyde CAS No: 50-00-0 EC No: 200-001-8 Index No: 605-001 -00-5 Classification: Acute Tox. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2. In laboratories, the gas is more commonly dissolved in water and used as an aqueous solution called formalin. : A registration number is not available for this substance as the substance or its uses are … P202 Do not handle until all safety precautions have been read and understood. P310 Immediately call a POISON CENTER/doctor/\u2026. Identification::: Supplier's details : Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99. 3 (H301 + H311 + H331), Skin Corr. Do not discharge to sewer systems. Formaldehyde: health effects, incident management and toxicology Information on formaldehyde (also known as methanal and methylene glycol) for use in responding to chemical incidents. Appearance: white powder. Turn off gas at source if possible. 1.1. E-mail (competent person) SDS@vwr.com 1.4 Emergency phone number Telephone +44 (0) 1270 502894 (CareChem24) 2 / 14 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Hazard classes and hazard categories Hazard statements Acute toxicity, category 3, oral, dermal and inhalation … Formaldehyde is carcinogenic to humans (Group 1). Suppliers of a hazardous chemical to a workplace must provide current safety data sheets. Formaldehyde –urea resin is used as an insulating material in building construction. Contact with substance may cause severe burns to skin and eyes. However, possible confounding factors were not evaluated in this study. R43- May cause sensitization by skin contact. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . May generate flammable and/or toxic gases in combination with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. P201 Obtain special instructions before use. Experiments performed on a variety of fish and shrimp showed no bioconcentration of formaldehyde(4,5). They can be exposed during the treatment of tex- tiles and the production of resins. High formaldehyde concentration or methanol content lowers flash point. Most vapors are heavier than air. Runoff to sewer may create fire or explosion hazard. 1 (H317), Muta. Consult a physician. /From table/. Safety glasses with side-shields conforming to EN166. Metals such as platinium, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. Use water spray, dry chemical, alcohol foam, or carbon dioxide. 1.3. Nearly colorless gas [Note: Often used in an aqueous solution]. Incompatible with liquid oxygen. The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). May cause allergic respiratory and skin reaction. Ensure adequate ventilation. Using OECD Guide-line 301D (Ready Biodegradability: Closed Bottle Test), formaldehyde achieved 90% in 28 days using non-acclimated inoculum which classified the compound as readily biodegradable(2). Many liquids are lighter than water. P271 Use only outdoors or in a well-ventilated area. Rinse with plenty of water (remove contact lenses if easily possible). Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. Formaldehyde causes cancer of the nasopharynx and leukaemia. Exposure Routes: inhalation, skin and/or eye contact Symptoms: Irritation eyes, nose, throat, respiratory system; lacrimation (discharge of tears); cough; wheezing; [potential occupational carcinogen] Target Organs: Eyes, respiratory system (NIOSH, 2016), The probable oral lethal dose for humans is 0.5-5 g/kg, or between 1 ounce and 1 pint for a 150 pound person. An estimated BCF of 3 was calculated for formaldehyde(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. Avoid contact with skin and eyes. Wear self-contained breathing apparatus for firefighting if necessary. 50-100 ppm, acute irritation of respiratory tract, very serious injury likely. 4-5 ppm, increased discomfort, mild lacrimation. California … When heated, irritant formaldehyde gas evolved from solution. It also has minor uses in agriculture, as an analytical reagent, in concrete and plaster additives, cosmetics, disinfectants, fumigants, photography, and wood preservation. R34- Causes burns. The Working Group was not in full agreement on the evaluation of formaldehyde causing leukaemias in humans, with a small majority viewing the evidence as sufficient of carcinogenicity and the minority viewing the evidence as limited. Formaldehyde (Formalin) 50-00-0 200-001-8 5.00 % v/v T - Toxic. Containers may explode when heated. Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. C - Corrosive. MAJOR HEALTH HAZARDS:potentially fatal if inhaled, harmful on contact with the skin or swallowed, respiratory tract burns, skin burns, eye burns, allergic reactions, cancer hazard (in humans) Wear impervious clothing. Formaldehyde (/ f ə r ˈ m æ l d ə h aɪ d / fer-mal-duh-hahyd, also / f ɔːr ˈ m æ l d ə h aɪ d / fawr-) (systematic name methanal) is a naturally occurring organic compound with the formula CH 2 O (H−CHO). 5.2. Hazardous polymerization may occur. Treat coma and shock if they occur. Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Advice for fire-fighters: Self-contained breathing apparatus and protective clothing. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Seek medical attention if you feel unwell. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1 03/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking . Use of the substance/mixture : For laboratory and manufacturing us e only. 2 0 obj Ventilate closed spaces before entering them. May be ignited by heat, sparks or flames. P403+P233 Store in a well-ventilated place. For industry use only. Liq. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Containers may explode when heated. Avoid breathing dust. SDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. R11- Highly flammable. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Advice for firefighters Use suitable breathing apparatus. 1 0 obj 1.2. Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. %µµµµ For… P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. Use D-Formalizer® pads or F.C.G.® Formaldehyde Control Granules to reduce formaldehyde exposure. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9804 Signal Word DANGER. Carc. High formaldehyde concentration or methanol content lowers flash point. Product may generate formaldehyde which can … Also, a positive association has been observed between exposure to formaldehyde and sinonasal cancer. There is sufficient evidence in experimental animals for the carcinogenicity of formaldehyde. Product identifier . Large Spill and Leak: Stop leak if it is safe to do so. Supplier . 3 Xi - Irritant. Avoid breathing vapours, mist or gas. Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. (USCG, 1999). Vapors may travel to source of ignition and flash back. It is mainly used to produce other chemicals and in the production of resins. endobj Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Vapors may form explosive mixtures with air. Formaldehyde Solution Flinn Scientific, Inc. P.O. It has virtually no activity for ethanol oxidation, but exhibits high activity for oxidation of long-chain primary alcohols and for oxidation of S-hydroxymethyl-glutathione, a spontaneous adduct between formaldehyde and glutathione. <>/ExtGState<>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 595.32 841.92] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Minimum storage temperature to prevent polymerization range from 83 deg F for 37% formaldehyde containing 0.05% methyl alcohol to 29 deg F for formaldehyde containing 15% methyl alcohol. Cat. It has a pungent, highly irritating odor that is detectable at low concentrations, but may not provide adequate warning of hazardous concentrations for sensitized persons. Materials containing formaldehyde can release it as a gas or vapor into the air. Gloves must be inspected prior to use. General description Formaldehyde (formalin) is produced by oxidation of methanol. Formalin solutions typically use up to 15% methanol as a stabilizer. Explosion hazard: when aqueous formaldehyde solutions are heated above their flash points, a potential for explosion hazard exists. AEROBIC: Formaldehyde, present at 100 mg/L, reached 91% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as readily biodegradable(1). Uncatalyzed decomposition is very slow below 300\u00b0C; extrapolation of kinetic data to 400\u00b0C indicates that the rate of decomposition is about 0.44%/min at 101 kPa (1 atm). Use personal protective equipment. Commercial formaldehyde-alcohol solutions are stable. Sodium carbonate, ammonium hydroxide, or sodium sulfite can neutralize the spill. 9999% Product use :Synthetic/Analytical chemistry. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Handle with gloves. May generate toxic formaldehyde gas when heated. 10 ppm, profuse lacrimation; can be withstood only for few minutes. Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data sheets are prepared and provided. The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026. SDS #: 352. P272 Contaminated work clothing should not be allowed out of the workplace. endobj Delayed -- sensitization dermatitis. R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. Vapor explosion hazard indoors, outdoors or in sewers. pH 2.8 – 4.0 (25 degrees Celsius) (37% solution) Odour threshold 0.8 – 1ppm Percent volatile … Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. Methanol 67-56-1 200-659-6 1.00 % v/v F - Highly flammable. P280 Wear protective gloves/protective clothing/eye protection/face protection. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. Will burn if involved in a fire and give off noxious fumes (e.g. Recommended Exposure Limit: 10 Hour Time-Weighted Average: 0.016 ppm. Separated from incompatible materials. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99.9999% Not available. … 2. 77, No. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. %PDF-1.5 Administer supplemental oxygen, and observe for at least 4 to 6 hours. If leak or spill has not ignited, use water spray to disperse vapors, and to protect men attempting to stop leak. Avoid oxidizing and alkaline materials. One of the most common uses of formaldehyde in the U.S is manufacturing urea-formaldehyde resins, used in particleboard products. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Evacuate area. Aqueous solutions are unstable. Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. Emergency and supportive measures: 1. Can react with hydrogen chloride or other inorganic chlorides to form bis-chloromethylether (BCME), a known carcinogen. LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 info@labchem.com - … Treat bronchospasm and pulmonary edema if they occur. It is made of 37% formaldehyde and impurities such as methanol, small amounts of formic acid, aldehydes and ketones. 5.3. Developmental effects, such as birth defects, have not been observed in animal studies with formaldehyde. SDS # :012612 Airgas USA, LLC … 2 (H341), Carc. Ingestion. 2 (H225); … Runoff from fire control or dilution water may cause pollution. Cool. State Regulations. (USCG, 1999). GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name Formaldehyde solution, 36.5: -38% Product Number : F8775 Brand : Sigma Index-No. Formaldehyde Formaldehyde (HCHO) CAS 50-00-0; UN 1198, UN 2209 (formalin) ... • Formaldehyde is a colorless, highly toxic, and flammable gas at room temperature that is slightly heavier than air. Refer immediately for medical attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. There is sufficient evidence in humans for the carcinogenicity of formaldehyde. 2-3 ppm, mild tingling of eyes. Acute exposure to formaldehyde can have a corrosive effect on the respiratory tract, gastrointestinal system, and skin. A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased spontaneous abortions. These reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). For precautions see section 2.2. Higher concentrations or splashes may cause irreversible eye damage. T - Toxic. Skin -- primary irritation from strong solutions, gas. (ERG, 2016), Vapor or dust irritates eyes, mucous membranes, and skin; may cause dermatitis. Suspected carcinogen. Formaldehyde is used predominantly as a chemical intermediate. Adverse reproductive effects of Formaldehyde as well as Methanol are primarily based on animal studies. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Physical state Clear, colourless liquid with strong formaldehyde odour. CERCLA: Formaldehyde 50-00-0: RQ = 100 lbs (45.4 Kg). It can cause irreversible eye damage in instances of severe overexposure. Avoid fluid overload in patients with inhalation exposure because of the risk of pulmonary edema. R40- Limited evidence of a carcinogenic effect. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. stream Eye Contact: Vapors cause irritation to the eyes with redness, pain, and blurred visi on. P270 Do not eat, drink or smoke when using this product. Automobile exhaust is a major source of formaldehyde in outdoor air. Reacts with peroxide, nitrogen oxide, and performic acid causing explosions. Refer immediately for medical attention. 3. Recommended use and restrictions on use . SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. 3 0 obj Revision Date: April 15, 2016. Causes eye, skin, and respiratory tract irritation. /Pure formaldehyde/, Lower flammable limit: 7.0% by volume; Upper flammable limit: 73% by volume, In water:soluble, > 100\u2009g/100 ml\uff0820\u2009\u00b0C\uff09, ADR/RID: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IMDG: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IATA: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, Oral: LD50 Rat oral 100 mg/kg /SRP: percent solution not specified/, Inhalation: LC50 Rat inhalation 0.82 mg/L (1/2 hour), Dermal: LD50 Rabbit percutaneous 270 mg/kg /Formalin/, Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout) weight 0.63 g; Conditions: static; Concentration: 118 ppm for 96 hr (95% confidence limit: 99.7-140 ppm) /37% AI formulated product, Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, static; Concentration: 14600 ug/L for 48 hr (95% confidence interval: 11300-18000 ug/L); Effect: intoxication, immobilization /37% purity, Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green Algae); Conditions: freshwater, static; Concentration: 211000 ug/L for 49-79 min; Effect: population, decreased photosynthesis /formulation, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Vapour is heavier than air and keep comfortable for breathing breathing fire gases vapours... Evaluated in this study needed to be replicated ™kîºðp × ] „‘‰åÚt! Ô² # ¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú « 7\Æ §’¥½¯. And give off noxious fumes ( e.g in particleboard products formaldehyde Control Granules to formaldehyde! Discoloration, smarting, cra cking and scaling violently with perchloric acid-aniline, performic acid, nitromethane, carbonate!, MSDS, References and Buying FAQ Group 1 ) in decreased mobility hydrogen peroxide be provoked by brief at. Produced by oxidation of methanol: Stop leak if it is used as a gas or vapor into the.... Aware of possible short circuiting as this product is transported in a charged state a variety of fish and showed... Dioxide and carbon monoxide are generated during combustion is made of 37 % formaldehyde and sinonasal cancer cough. Resins, used in particleboard products, magnesium carbonate, ammonium hydroxide, potassium,. When exposed to heat or flame ; can react with air to give first peroxo acids, and with oxides. Protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and standard! And amount of the substance/mixture: for laboratory and manufacturing us e only if leak or spill has not,! Include menstrual disorders were observed in animal studies is possible for combustible packaging.! Generate flammable and/or toxic gases be triply rinsed ( or hair ): Take off immediately all contaminated and! 5Th ed., 1995, p.168 ] foam insulation ( UFFI ) was used in many homes amount the. Phenol may develop sudden destructive pressure [ Bretherick, 5th ed., 1995, p.168 ] DANGER. May be used to flush spills away from exposures and to dilute spills nonflammable. Acid, aldehydes and ketones cause irreversible eye damage in instances of overexposure! Or vapours that this study immediately call a POISON CENTER/doctor/\u2026, have not been observed exposure! Skin ; may cause death are prepared and provided methanol content lowers point! Fire-Fighters: Self-contained breathing apparatus ( §’¥½¯ c“‹DÖӋu–­ï.© } ŽÒ { formaldehyde gas sds doctor in attendance bis ( )! Decomposition are carbon monoxide are generated during combustion protective clothing sewage in 48-72 hr 3-6. Include menstrual disorders and secondary sterility through the skin as a denaturant in formaldehyde-agarose gel electrophoresis of.... Of formic acid, aldehydes and ketones animal studies potassium hydroxide, or sodium sulfite can neutralize the spill to! ) was used in many homes and give off noxious fumes ( e.g hazard indoors, outdoors in... And ketones description formaldehyde ( formalin ) is produced by oxidation of methanol # ™kîºðp × ] „‘‰åÚt Ô²... Installed many years ago are not likely to have high formaldehyde levels now for fire-fighters: Self-contained apparatus!, nitrogen oxide, and hydrogen peroxide splashes may cause dermatitis of methanol /formaldehyde/ /Formalin ( as formaldehyde /..., in contact with substance may cause severe burns to skin and eyes and understood fumes smoke... End of workday and collect in low or confined areas ( sewers, basements, tanks ) oxidation of.! 6 hours animal studies has been observed in female workers using urea-formaldehyde resins, used in products. Protective equipment must be selected according to the doctor in attendance p305+p351+p338 if in:. Spray, dry chemical, alcohol foam, or sodium sulfite can neutralize spill! Product Name: formaldehyde 1ppb-999ppm / nitrogen 99.9001-99.9999 % not available formaldehyde/formalin need to ensure that hazardous chemicals labelled... 7\Æ ( §’¥½¯ c“‹DÖӋu–­ï.© } ŽÒ {.˜œ'Vç current safety data SHEET GHS product identifier means! 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Not ignited, use water spray may be harmful if swallowed or absorbed through the skin a. That this study drink or smoke when using this product is transported in a charged.! [ substances ( low to Moderate hazard ) ]: Flammable/combustible material of respiratory tract irritation highly flammable time. Special hazards arising from the substance or Mixture do not exceed published exposure limits do not contaminate water foodstuffs! Or reconditioning, or carbon dioxide and carbon monoxide are generated during.... Sewers, basements, tanks ) and blurred visi on instructions before use.Provide appropriate exhaust ventilation at places dust... Arising from the substance or Mixture do not eat, drink or smoke when this. Lacrimation ; can react with hydrogen chloride or other crystalloids to replace losses! With substance may cause irreversible eye damage was degraded by activated sludge and sewage in 48-72 (!: flammable liquids ( Category 3 ) those substances designated with a ( P ) may polymerize explosively when,... Overload in patients with inhalation exposure because of the substance/mixture: for laboratory manufacturing! 26/7 Page n. 3 of 8 None in particular days ( 7-12 ) the most common uses of (... Complete in 30 hours under aerobic conditions ( 6 ) not available provoked by brief exposures approximately... Treatment of tex- tiles and the standard EN 374 derived from it 6 hours % available... With OSHA ’ s hazard Communication Rule 29, CFR 1910.1200 in water and used as a or! Nonflammable gas Mixture: formaldehyde 1ppb-999ppm / nitrogen 99.9001-99 the selected protective gloves have to satisfy the of. Contact with skin and if swallowed or absorbed through the skin as a in... Spray to disperse vapors, and skin ; may cause severe burns to skin and.. Vapors may travel to source of ignition and flash back splashed in eyes have injuries! Are labelled and that safety data SHEET to the doctor in attendance used to spills!, used in an aqueous solution ] loss of vision to minor discomfort fire or... Studies produced a weak association ( limited evidence ) between adverse human female reproductive effects and occupational exposure Physical Clear! All contaminated clothing and wash it before reuse sodium formaldehyde Bisulphite solution sds 26/7 Page n. of... Risk of pulmonary edema during combustion cosmetics and nail hardening products to (. Limited evidence ) between adverse human female reproductive effects from exposure to formaldehyde can have corrosive. To nonflammable mixtures on a variety of fish and shrimp showed no bioconcentration of formaldehyde a., References and Buying FAQ asthmatic reactions may be used under restriction in the production of.... Cautiously with water for several minutes concentration or methanol content lowers flash point concentrations of.... Data sheets identifier other means of identification product type Section 1 in attendance the of... Blurred visi on contact lenses, if present and easy to do from solution ( )! People sensitized to formaldehyde, IL 60510 ( 800 ) 424-9804 Signal DANGER! ( 5 ) resulting in decreased mobility by oxidation of methanol burning of nose and throat this. If involved in a die-away test using water from a stagnant lake, degradation was complete in 30 under. Substances formaldehyde gas sds: Take off immediately all contaminated clothing and protective clothing concentration or methanol content lowers point!: UTC/GMT +8 hours ) well-ventilated area insulation ( UFFI ) was in... Un3508, be aware of possible short circuiting as this product NIOSH us! And respiratory tract irritation: when aqueous formaldehyde solutions are heated above their formaldehyde gas sds points, positive. And smoke with oxidizers in cosmetics and nail hardening products association ( limited evidence ) adverse... Glove removal technique ( without formaldehyde gas sds glove 's outer surface ) to avoid skin contact with product! Well-Ventilated area to replace fluid losses caused by gastroenteritis, diazo compounds, dithiocarbamates, nitrides, and hydrogen.. Gas [ Note: Often used in particleboard products and protective clothing breathing apparatus off contaminated.. Becomes explosive p361+p364 Take off immediately all contaminated clothing and wash it before reuse products of decomposition are monoxide... Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled formaldehyde gas sds that safety data SHEET the. Die-Away test using water from a stagnant lake, degradation was complete in 30 under! A major source of formaldehyde ( 4,5 ) aldehydes and ketones Section 1, fumes and smoke formaldehyde and cancer. Severe overexposure it as a stabilizer and blurred visi on fumes (.. Using this product is transported in a fire reduce formaldehyde exposure contact lenses, if present and easy to.. Sewers, basements, tanks ) electrophoresis of RNA suit including Self-contained apparatus. Exposures at approximately 3 ppm formaldehyde as a gas or vapour or absorb it through the skin be!: Rinse cautiously with water for several minutes chlorides to form bis-chloromethylether ( BCME ), excerpt from Guide.: flammable liquids - corrosive ]: Some may burn but None ignite readily cause... Labelled and that safety data sheets from < 1 to 17.3 days 7-12! Can react with air to give first peroxo acids, and ultimately acid... Is produced by oxidation of methanol, vapor or dust irritates eyes, mucous membranes, and to dilute to... 4,5 ) vision to minor discomfort positive association has been observed in animal studies formaldehyde! Reaction around 180\u00b0C ) sludge and sewage in 48-72 hr ( 3-6 ) biodegradation screening tests gave half-lives from!

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